- Title
- Analysis of the formation of hollow nanocrystals: theory and Monte Carlo simulation
- Creator
- Belova, Irina V.; Murch, G. E.
- Relation
- Journal of Phase Equilibria and Diffusion Vol. 26, no. 5, p. 430-434
- Publisher
- ASM International
- Resource Type
- journal article
- Date
- 2005
- Description
- Experiments on the formation of hollow nanocrystals by way of Kirkendall porosity resulting from a vary large Kirkendall effect have been reported recently by Yin et al. (Science, Vol 304, 2004, p 711). In the present paper, there is a discussion of some theoretical aspects of this process using chemical diffusion theory in the formal absence of vacancies at equilibrium. A formal description of the observed nanoscale Kirkendall effect is given that accompanies this process. A set of Monte Carlo simulations of the process are performed to verify the theoretical findings.
- Identifier
- uon:70
- Identifier
- http://hdl.handle.net/1959.13/24443
- Identifier
- ISSN:1547-7037
- Language
- eng
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