- Title
- Ultrasound-assisted synthesis of Dy2Mo3O12-Dy2O3 nanostructures for enhanced electrochemical hydrogen storage
- Creator
- Morassaei, Maryam Sadat; Salehabadi, Ali; Akbari, Ahmad; Dawi, Elmuez A.; Aljeboree, Aseel M.; Altimari, Usama S.; Salavati-Niasari, Masoud
- Relation
- International Journal of Hydrogen Energy Vol. 64, Issue 25 April 2024, p. 766-772
- Publisher Link
- http://dx.doi.org/10.1016/j.ijhydene.2024.03.333
- Publisher
- Elsevier
- Resource Type
- journal article
- Date
- 2024
- Description
- Among the major challenges facing the hydrogen economy is the issue of hydrogen storage. In terms of "future energy needs", electrochemical hydrogen storage in solid-state materials is an accepted perspective that could mitigate the discontinuation of primary energy sources. In this study, we demonstrate the electrochemical properties of a complex metal oxide that contains the molybdate group, Dy2Mo3O12. Wet-chemical synthesis of nanostructured Dy2Mo3O12 is primarily carried out using ultrasound-assisted wet-chemical methods in the presence of a variety of surfactants. The structural and morphological observations of the samples confirm a pure and highly crystalline structure obtained in the presence of CTAB surfactant at 900 ◦C and 30 min of sonication, with an average crystalline size of 29 nm. Based on the FTIR spectrum of this sample, it can be concluded that there are significant absorptions indicating the formation of oxygen-metal bonds. The specific surface area and pore volume of the selected sample are 4.543 m2/g and 0.0284 cm3/g, respectively, demonstrating its porous structure. Electrochemical studies of this sample at various temperatures have revealed an enhanced discharge capacity (5100 mAh/g at 65 ◦C) with a capacity retention rate of 97%. Based on these findings, mixed metal oxides containing at least one active charge transfer species (Red./Ox.) are suitable for use in solid-state hydrogen storage devices.
- Subject
- Dy2Mo3O12-Dy2O3; nanostructures; garnet; electrochemical hydrogen storage; sonochemical synthesis; SDG 7; Sustainable Development Goals
- Identifier
- http://hdl.handle.net/1959.13/1506554
- Identifier
- uon:55903
- Identifier
- ISSN:0360-3199
- Language
- eng
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