- Title
- Soil washing of arsenic from mixed contaminated abandoned mine soils and fate of arsenic after washing
- Creator
- Bari, A. S. M. Fazle; Lamb, Dane; MacFarlane, Geoff R.; Rahman, Mohammad Mahmudur
- Relation
- Chemosphere Vol. 296, no. 134053
- Publisher Link
- http://dx.doi.org/10.1016/j.chemosphere.2022.134053
- Publisher
- Elsevier
- Resource Type
- journal article
- Date
- 2022
- Description
- Arsenic contamination in abandoned soils is a global concern which warrants an effective method of remediation. In this study, two organic acids and one biodegradable chelating agent were used to treat arsenic (As) contaminated abandoned mine soils. The concentration of As was 19,100 and 75,350 (mg/kg) for Webbs Consols (WC) and Mole River (MR) samples, respectively. X-ray diffraction and scanning electron microscopy confirmed that tooeleite, arsenopyrite, scorodite and quartz were the major minerals in these soils. A major portion of the As was composed of amorphous and crystalline oxides of Fe and Al determined by sequential extraction. Among the three washing reagents (oxalic acid, citric acid and EDDS) oxalic acid showed the best performance for extracting As. Based on the batch experiment, 0.5 M oxalic acid and 3 h of washing was the most efficient treatment to extract As and other trace elements. Extraction of As, Fe, and Pb was 70, 55, and 48% respectively for WC, while 68, 45 and 63% respectively for MR soil. Oxalic acid extracted 75 and 83% of As and Fe, respectively from tooeleite. Leachability and bioaccessibility of As and Fe in the treated soil was reduced due to washing. However, bioaccessibility and leachability of Pb in soil and Fe and As in tooeleite increased in washed samples. Though the leachability and bioaccessibility of As and Fe in soil was reduced in the treated soil, As still exceeded the USEPA criteria (5 mg/L) which is needed to successfully remediate soil by washing. Soil washing and subsequent solidification/stabilization could be an alternative option to remediate extremely contaminated abandoned mine soil.
- Subject
- arsenic; abandoned mine soil; soil washing; organic acid; leachability; bioaccessibility
- Identifier
- http://hdl.handle.net/1959.13/1464486
- Identifier
- uon:47014
- Identifier
- ISSN:0045-6535
- Language
- eng
- Reviewed
- Hits: 545
- Visitors: 545
- Downloads: 0