- Title
- Enhancing the selectivity of H₂O₂ electrogeneration by steric hindrance effect
- Creator
- Xiao, Xue; Wang, Tianjiao; Bai, Juan; Li, Fumin; Ma, Tianyi; Chen, Yu
- Relation
- ARC.DE150101306 http://purl.org/au-research/grants/arc/DE150101306
- Relation
- ACS Applied Materials and Interfaces Vol. 10, Issue 49, p. 42534-42541
- Publisher Link
- http://dx.doi.org/10.1021/acsami.8b17283
- Publisher
- American Chemical Society
- Resource Type
- journal article
- Date
- 2018
- Description
- Selective hydrogen peroxide (H₂O₂) electrogeneration by oxygen reduction reaction (ORR) is an efficient and promising synthetic method for H₂O₂ production. Herein, we build a particular inorganic-organic interface to enhance the electrocatalytic selectivity of reduced graphene oxide (rGO) aerogels for H₂O₂ electrogeneration by modifying rGO aerogels with polyethyleneimine (PEI). The three-dimensional porous structure of aerogels and the steric hindrance effect of PEI on rGO endow PEI-functionalized rGO (rGO/PEI) aerogels with enhanced selectivity (90.7%), production rate (106.4 mmol gcat-1 h-1), and durability for H₂O₂ electrogeneration by the two-electron pathway of ORR.
- Subject
- H₂O₂ electrogeneration; oxygen reduction reaction; inorganic−organic interface; steric hindrance effect; selectivity
- Identifier
- http://hdl.handle.net/1959.13/1405776
- Identifier
- uon:35548
- Identifier
- ISSN:1944-8244
- Rights
- This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in ACS Applied Materials and Interfaces Journal, copyright © American Chemical Society after peer review. To access the final edited and published work see: http://dx.doi.org/10.1021/acsami.8b17283
- Language
- eng
- Full Text
- Reviewed
- Hits: 4207
- Visitors: 4479
- Downloads: 293
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | ATTACHMENT02 | Author final version | 1 MB | Adobe Acrobat PDF | View Details Download |