- Title
- Oxidative coupling and hydroxylation of phenol over transition metal and acidic zeolites: insights into catalyst function
- Creator
- Li, Jerry Pui Ho; Kennedy, Eric; Stockenhuber, Michael
- Relation
- Catalysis Letters Vol. 144, Issue 1, p. 9-15
- Publisher Link
- http://dx.doi.org/10.1007/s10562-013-1142-z
- Publisher
- Springer
- Resource Type
- journal article
- Date
- 2014
- Description
- Reaction of phenol with hydrogen peroxide over H-MFI, Fe-MFI, H-BEA, Fe-BEA and TS-1 zeolite catalysts was investigated. Over H-BEA, biphenyl product was observed. It is suggested, that the larger pore size of H-BEA facilitates coupling of two phenol molecules. Two distinct reaction mechanisms are proposed for acid and redox catalysts.
- Subject
- catalysis; zeolites; phenol; hydroxylation; redox; pore size
- Identifier
- http://hdl.handle.net/1959.13/1307241
- Identifier
- uon:21372
- Identifier
- ISSN:1011-372X
- Language
- eng
- Reviewed
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