A speciation study of sulfur₍ᵢᵥ₎ in aqueous solution

Title: A speciation study of sulfur₍ᵢᵥ₎ in aqueous solution
Creator: Beyad, Yaser; Burns, Robert; Puxty, Graeme; Maeder, Marcel
Relation: Dalton Transactions Vol. 43, Issue 5, p. 2147-2152
Publisher Link: http://dx.doi.org/10.1039/c3dt52890a
Publisher: RSC Publications
Resource Type: journal article
Date: 2014
Description: In the current work ultraviolet spectrophotometric titrations at different S₍ᵢᵥ₎ concentrations have been globally analysed using the entire spectral dataset to determine the complete speciation of S₍ᵢᵥ₎ in aqueous solution over a large pH range (from 9.6 to 1). As a result, the dimerisation constant for the formation of disulfite from hydrogen sulfite has been accurately determined. Further, protonated disulfite has been identified and quantified for the first time. In addition, the molar absorptivities of all S(ᵢᵥ) species are also reported over the studied wavelength range.
Identifier: http://hdl.handle.net/1959.13/1293924
Identifier: uon:18696
Identifier: ISSN:1477-9226
Language: eng
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